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First of all I am a noob i dont know much about this stuff thats why im here to request for help from yall. My problem is that whenever i try to install for example Photoshop CS6 it asks to "Please select Adobe Photoshop CS6 install file" and when I click browse to find it, I can't seem to find it anywhere. Because of that i can seem to install anything. Hopefully someone can help me out with this. Thank you in advance.

Are you trying to do a manual installation or using one of the provided PlayOnLinux scripts?

You should save the Photoshop installer on your Linux Desktop.  So when you click "browse" you navigate to your Desktop.  The only other thing I can think of is the Photoshop installer is a .msi instead of a .exe, There is a chance PlayOnLinux doesn't know how to install a .msi file.